文献类型：期刊文献

中文题名：有机硅油改性聚醋酸乙烯乳液的合成及性能

英文题名：SYNTHESIS AND PERFORMANCE OF SILICONE OIL MODIFIED POLYVINYL ACETATE EMULSION

作者：刘德峥[1]

第一作者：刘德峥

机构：[1]平原大学化学工程系

第一机构：新乡学院化学化工学院

年份：2002

期号：3

起止页码：32-34

中文期刊名：精细石油化工

外文期刊名：Speciality Petrochemicals

收录：CSTPCD;;Scopus;北大核心:【北大核心2000】；CSCD:【CSCD_E2011_2012】；

语种：中文

中文关键词：有机硅油;改性;聚醋酸乙烯乳液;合成;性能;聚乙烯醇;抗水性;抗冻性;抗蠕变性;乳液胶粘剂

外文关键词：polyvinyl acetate emulsion; polyvinyl alcohol; silicone oil; waterproof property; anti freezing proparty; creep resistance

摘要：通过对聚乙烯醇的缩醛化 ,用种子乳液聚合的方法研制了有机硅油改性聚醋酸乙烯乳液。在实验条件为m (醋酸乙烯 )∶m (硅油 ) =1.0∶0 .0 81,胶核和外壳的反应温度分别为 70℃和 75℃ ,反应时间分别为 1.5h和 4h情况下 ,改性后的PVAc乳液与普通乳液相比具有较好的稳定性、成膜性、抗冻性、抗水性和抗蠕变性。乳液在 - 8～ - 5℃不冻结 ,胶膜吸水率由 30 .2 2 %下降到 10 .4 4 %。
A new kind of silicone oil modified polyvinyl acetate emulsion were synthesized. The defects of common polyvinyl acetate emulsion were successfully improved by the acetalation of polyvinyl alcohol as stabilizing agent in emulsion polymerization. The optimum reaction conditions were as follows: m(VAc)∶m(silicone oil)=1.0∶0.081, the reaction temperatures of the core and the shell were 70 ℃ and 75 ℃ respectively, the reaction time were 1.5 h and 4 h respectively.