文献类型：期刊文献

英文题名：Preparation and Crystal Structural Study of a Novel Coordinated Polymer [HgI2(4-bped)(2)] (bped = bis(4-pyridyl)ethylene diamine)

作者：Liang, Yu[2];Zhao, Fukai[1];Wang, Qingli[1];Niu, Yunyin[1]

第一作者：梁宇

通讯作者：Niu, YY[1]

机构：[1]Zhengzhou Univ, Dept Chem, Zhengzhou 450052, Henan, Peoples R China;[2]Xinxiang Univ, Coll Chem & Chem Engn, Xinxiang 453000, Peoples R China

第一机构：Zhengzhou Univ, Dept Chem, Zhengzhou 450052, Henan, Peoples R China

通讯机构：[1]corresponding author), Zhengzhou Univ, Dept Chem, Zhengzhou 450052, Henan, Peoples R China.

年份：2011

卷号：41

期号：6

起止页码：763-766

外文期刊名：JOURNAL OF CHEMICAL CRYSTALLOGRAPHY

收录：;Scopus(收录号：2-s2.0-79958065273);WOS:【SCI-EXPANDED(收录号:WOS:000290575700001)】；

基金：We gratefully acknowledge the financial support of The National Science Foundation of China (20671083).

语种：英文

外文关键词：Coordinated polymer; Crystal structure; HgI2 adducts; Metallamacrocycle

摘要：A novel coordinated polymer [HgI2(4-bped)(2)] was synthesized through the reaction of bis(4-pyridyl) ethylene diamine and HgI2 in mixed MeOH-THF (5:2). The crystal structural analysis indicated that the complex crystallized in a monoclinic space group P2(1)/c, a = 10.8392(12), b = 19.841(2), c = 8.8279(10), beta = 95.452(2), V = 1889.9(4) angstrom(3), Z = 4. The complex possessed a novel three-dimensional supramolecular framework formed by hydrogen bonds among repeating [HgI2(4-bped)](2) dimeric units.