文献类型：期刊文献

中文题名：离子液体中合成己二酸

英文题名：Synthesis of Adipic Acid in Ionic Liquid

作者：姚文惠[1]

第一作者：姚文惠

机构：[1]新乡学院建筑工程系

第一机构：新乡学院土木工程与建筑学院

年份：2009

卷号：26

期号：1

起止页码：30-31

中文期刊名：新乡学院学报

语种：中文

中文关键词：离子液体;己二酸;环己酮;NaWO4.2H2O;30%H2O2

外文关键词：ionic liquid; adipic acid; cyclohexanol; tungsten trioxide; 30% of hydrogen peroxide

摘要：在处于室温条件下的离子液体中,以NaWO4.2H2O为催化剂,H2O2为氧化剂,用环己酮合成己二酸。讨论了离子液体用量、NaWO4.2H2O用量、H2O2用量以及回收离子液体的使用等条件对反应的影响。此法后处理简便,产品收率高(70.5%)。
In room temperature ionic liquid, adipic acid was synthesized by oxidation of cyelohexanone. In this reaction 30% hydrogen peroxide was used as oxidant and NaWO4 · 2H2O as catalyst. Through an effort to optimize the reaction conditions, such as the reused ionic liquid, the amount of 30% hydrogen peroxide, NaWO4 · 2 H2O and the ionic liquid, we obtained the best result. This method has the advantage of being a green process along with mild reaction conditions and excellent yields （70.5 %）.