文献类型：期刊文献

英文题名：SYNTHESIS OF ZIRCONIUM BASED METAL ORGANIC FRAMEWORKS (MOFS): BASED ON BOX-BEHNKEN DESIGN

作者：Guo, Jiao[1,2];Zhang, Yakun[1];Zhang, Wei[1];Miao, Yu[1,2];Lu, Tiantian[1];Xia, Ji[1]

第一作者：郭娇;Guo, Jiao

通讯作者：Miao, Y[1]

机构：[1]Xinxiang Univ, Coll Chem & Chem Engn, Xinxiang 453003, Henan, Peoples R China;[2]Henan Photoelectrocatalyt Mat & Micronano Applica, Xinxiang 450003, Henan, Peoples R China

第一机构：新乡学院化学化工学院

通讯机构：[1]corresponding author), Xinxiang Univ, Coll Chem & Chem Engn, Xinxiang 453003, Henan, Peoples R China.|[110713]新乡学院化学化工学院;[11071]新乡学院;

年份：2019

卷号：28

期号：10

起止页码：7477-7482

外文期刊名：FRESENIUS ENVIRONMENTAL BULLETIN

收录：;Scopus(收录号：2-s2.0-85073504176);WOS:【SCI-EXPANDED(收录号:WOS:000487347700058)】；

基金：This work was financially supported by the National Natural Science Foundation of China (NSFC 51701173 and 51802275), A Project of Henan Province Science and Technology Program (182102311119), the Key Research Project of Chinese Universities (19B150016) and the Scientific Research Foundation of Xinxiang University (1366020019 and 15ZA03).

语种：英文

外文关键词：Microwave; Synthesis; Metal organic frameworks (MOFs); porous coordination

摘要：Microwave-assisted synthesis of zirconium (Zr) based metal organic frameworks (MOFs) were performed and the yield and porous property of UiO-67 was optimized by varying the quantity of the modulator, reaction time and temperature. It was found that (i) an increase in the amount of modulator enhanced the specific surface area and pore volume of UiO-67 due to the promotion of linker deficiency; and (ii) the presence of modulators influenced the number of nuclei (and hence the crystal size) and the yield.