文献类型：期刊文献

英文题名：Diaryl sulfones synthesis with aryltrifluoroborates and aryl sulfinic salts under mild conditions

作者：Zhang, Wei[1];Li, Ke[4];Zhao, Baoli[2,3]

第一作者：张伟

通讯作者：Zhao, BL[1]

机构：[1]Xinxiang Univ, Dept Chem & Chem Engn, Xinxiang 453003, Peoples R China;[2]Shaoxing Univ, Inst Appl Chem, Shaoxing 312000, Zhejiang, Peoples R China;[3]Shaoxing Univ, Dept Chem, Shaoxing 312000, Zhejiang, Peoples R China;[4]Jiaozuo City Environm Protect Bur, Jiaozuo 453003, Henan Province, Peoples R China

第一机构：新乡学院化学化工学院

通讯机构：[1]corresponding author), Shaoxing Univ, Inst Appl Chem, Shaoxing 312000, Zhejiang, Peoples R China.

年份：2014

卷号：38

期号：5

起止页码：269-271

外文期刊名：JOURNAL OF CHEMICAL RESEARCH

收录：;Scopus(收录号：2-s2.0-84901050797);WOS:【SCI-EXPANDED(收录号:WOS:000337747000003)】；

语种：英文

外文关键词：aryltrifluoroborates; aryl sulfinic salts; cross-coupling; diaryl sulfone synthesis

摘要：CuI-catalysed cross-coupling reactions of various aryltrifluoroborates with aryl sulfinic salts have been achieved in good yields. A new efficient method is described for the conversion of potassium aryltrifluoroborates into diaryl sulfones. The reported reactions are tolerant to common functional groups regardless of whether they are electron-rich or electron-deficient, making this transformation an attractive alternative to traditional approaches.