文献类型：期刊文献

英文题名：Ynones in Reflex-Michael Addition, CuAAC, and Cycloaddition, as Well as their Use as Nucleophilic Enols, Electrophilic Ketones, and Allenic Precursors

作者：Wang, Zhan-Yong[1];Wang, Kai-Kai[1];Chen, Rongxiang[1];Liu, Huan[1];Chen, Kaijun[2]

第一作者：王占勇

通讯作者：Wang, ZY[1];Chen, KJ[2]

机构：[1]Xinxiang Univ, Coll Chem & Chem Engn, Xinxiang 453000, Henan, Peoples R China;[2]Lishui Univ, Dept Chem, 1 Xueyuan Rd, Lishui 323000, Zhejiang, Peoples R China

第一机构：新乡学院化学化工学院

通讯机构：[1]corresponding author), Xinxiang Univ, Coll Chem & Chem Engn, Xinxiang 453000, Henan, Peoples R China;[2]corresponding author), Lishui Univ, Dept Chem, 1 Xueyuan Rd, Lishui 323000, Zhejiang, Peoples R China.|[110713]新乡学院化学化工学院;[11071]新乡学院;

年份：2020

卷号：2020

期号：17

起止页码：2456-2474

外文期刊名：EUROPEAN JOURNAL OF ORGANIC CHEMISTRY

收录：;Scopus(收录号：2-s2.0-85081242461);WOS:【SCI-EXPANDED(收录号:WOS:000530893200001)】；

基金：We thank the National Natural Science Foundation of China (21801214) and the Higher Education Institution Key Research Project Plan of Henan Province of China (18A150014) and Funding of National University Student Innovation Program (201911071001).

语种：英文

外文关键词：Tandem reactions; Michael addition; Enols; Terminal alkynes; Ynones

摘要：The great success of ynones in synthesis is rooted in their multiple functional groups. Herein, reactions triggered by the reflex-Michael addition, ynones in copper(I)-catalyzed alkyne-azide cycloaddition (CuAAC), and formal cycloaddition as well as the use of ynones as nucleophilic enols, electrophilic ketones, and allenic precursors were thoroughly discussed and summarized. Multi-component reactions, rearrangements, cycloadditions, regio- and stereoselective synthesis, coupling, and cycloaddition are depicted in detail. This review focused on advances of ynones chemistry in the last decade (2009-2019). We hope it will promote future research in this area.