文献类型：期刊文献

英文题名：Cobalt-catalyzed esterification-peroxidation of alpha-diazoesters: access to alpha-acyloxy esters

作者：Chen, Rongxiang[1];Ma, Guoyang[2];Zhang, Jinju[1];Wang, Zhan-Yong[1];Xu, Shaohong[1];Wang, Kai-Kai[1]

第一作者：Chen, Rongxiang

通讯作者：Xu, SH[1];Wang, KK[1]

机构：[1]Xinxiang Univ, Sch Pharm, Xinxiang 453003, Peoples R China;[2]Xinxiang Univ, Sch Chem & Mat Engn, Xinxiang 453003, Peoples R China

第一机构：新乡学院

通讯机构：[1]corresponding author), Xinxiang Univ, Sch Pharm, Xinxiang 453003, Peoples R China.|[11071]新乡学院;

年份：0

外文期刊名：NEW JOURNAL OF CHEMISTRY

收录：;WOS:【SCI-EXPANDED(收录号:WOS:000907182200001)，CCR-EXPANDED(收录号:WOS:000907182200001)】；

基金：We gratefully acknowledge financial support from the Natural Science Foundation of Henan (202300410016), the Program for Youth Backbone Teacher Training in University of Henan Province (2021GGJS163), and the Higher Education Institution Key Research Project Plan of Henan Province (23A150044).

语种：英文

摘要：A cobalt-catalyzed esterification-peroxidation was realized by a Co(ii)/TBHP system to deliver alpha-acyloxy esters from readily available starting materials in moderate to good yields. In this process, the O-H insertion reaction of diazo reagents, C-H activation and peroxidation were fused into a reaction system. Preliminary mechanistic studies show that a free-radical process is involved in this method.