文献类型：期刊文献

英文题名：Desulfitative palladium-catalyzed direct C-3 arylation of indolizines with arylsulfonyl chlorides

作者：Zhang, Wei[1];Liu, Fang[2];Zhao, Baoli[3,4]

第一作者：张伟

通讯作者：Zhao, BL[1]

机构：[1]Xinxiang Univ, Dept Chem & Chem Engn, Xinxiang 453003, Henan Province, Peoples R China;[2]Hebei North Univ, Life Sci Res Ctr, Zhangjiakou, Hebei Province, Peoples R China;[3]Shaoxing Univ, Inst Appl Chem, Shaoxing 312000, Zhejiang, Peoples R China;[4]Shaoxing Univ, Dept Chem, Shaoxing 312000, Zhejiang, Peoples R China

第一机构：新乡学院化学化工学院

通讯机构：[1]corresponding author), Shaoxing Univ, Inst Appl Chem, Shaoxing 312000, Zhejiang, Peoples R China.

年份：2015

卷号：29

期号：8

起止页码：524-527

外文期刊名：APPLIED ORGANOMETALLIC CHEMISTRY

收录：;EI(收录号：20152100871422);Scopus(收录号：2-s2.0-84937966936);WOS:【SCI-EXPANDED(收录号:WOS:000358533300006)，CCR-EXPANDED(收录号:WOS:000358533300006)】；

基金：This study was supported by the National Natural Science Foundation of China (no. 21402123), the Zhejiang Provincial Natural Science Foundation of China (no. LQ14B020001) and the Education Department of Zhejiang Province (no. Y201328443).

语种：英文

外文关键词：desulfitative arylation; indolizines; arylsulfonyl chlorides

摘要：An efficient Pd-catalyzed desulfitative approach to C-3 arylation of indolizine derivatives has been developed, and the protocol uses readily available arylsulfonyl chlorides as the arylation reagent under nitrogen. This transformation was performed in a mixed solvent of 1-methyl-2-pyrrolidone and dimethoxyethane using simple triphenylphosphine as a ligand, which provides a new method for the C-3 arylation of indolizines. Copyright (c) 2015 John Wiley & Sons, Ltd.