文献类型：期刊文献

英文题名：Synthesis, structures and properties of two novel supramolecular polymers of Cu(I) with 1,1 '-Bis(isoquinoline)-1,4-Phenyldimethylenyl

作者：Wang, Chaohai[1];Song, Lisha[1];Niu, Yunyin[1];Liang, Yu[2]

第一作者：Wang, Chaohai

通讯作者：Niu, YY[1]

机构：[1]Zhengzhou Univ, Coll Chem & Mol Engn, Zhengzhou 450052, Peoples R China;[2]Xinxiang Univ, Coll Chem & Chem Engn, Xinxiang, Peoples R China

第一机构：Zhengzhou Univ, Coll Chem & Mol Engn, Zhengzhou 450052, Peoples R China

通讯机构：[1]corresponding author), Zhengzhou Univ, Coll Chem & Mol Engn, Zhengzhou 450052, Peoples R China.

年份：2015

卷号：14

期号：1

起止页码：71-78

外文期刊名：MAIN GROUP CHEMISTRY

收录：;Scopus(收录号：2-s2.0-84915753196);WOS:【SCI-EXPANDED(收录号:WOS:000345980500007)】；

基金：Research efforts in the Niu group are supported by the National Science Foundation of China (No. 21171148), Foundation and Frontier Research Project of Henna Province (No. 132300410265) and Xinxiang Science and Technology Key projects Fund (ZG13012) and Zhengzhou University(13L00206).

语种：英文

外文关键词：Cationic templates; supramolecular polymer; self-assembly

摘要：Two new complexes {(BIQPM)(2)[Cu4I8]center dot DMF}(n) (1) and {(BIQPM)[Cu-2(SCN)(4)]}(n) (2) [ BIQPM = 1,1'-Bis(isoquinoline)-1,4-Phenyldimethylenyl] have been synthesized via the self-assembly reaction in solution. Single-crystal X-ray diffraction analysis shows compound 1 is a tetranuclear oligomer and 2 is a 1D chain. Compound 1 crystallizes in the monoclinic system with space group C2/m; Compound 2 crystallizes in the triclinic system with space group P-1. It is the H-bonds and electrostatic interactions between the organic counteractions and inorganic moieties that do the contribution to the crystal packing. These compounds have been further characterized by IR spectroscopy and thermostability.