文献类型：期刊文献

英文题名：A Three-Component Reaction to Construct beta-Aminonitroso-alpha-Diazocarbonyl Compounds under Metal-Free Conditions

作者：Chen, Rongxiang[1];Lan, Jihong[2];Li, Feng[1];Wang, Kai-Kai[1];Xue, Yinghui[1];Xu, Canran[1];Liu, Lantao[3]

第一作者：Chen, Rongxiang

通讯作者：Wang, KK[1];Liu, LT[2]

机构：[1]Xinxiang Univ, Sch Pharm, Xinxiang 453000, Henan, Peoples R China;[2]Xinxiang Univ, Sch Chem & Mat Engn, Xinxiang 453000, Henan, Peoples R China;[3]Shangqiu Normal Univ, Coll Chem & Chem Engn, Shangqiu 476000, Peoples R China

第一机构：新乡学院

通讯机构：[1]corresponding author), Xinxiang Univ, Sch Pharm, Xinxiang 453000, Henan, Peoples R China;[2]corresponding author), Shangqiu Normal Univ, Coll Chem & Chem Engn, Shangqiu 476000, Peoples R China.|[11071]新乡学院;

年份：2022

卷号：364

期号：8

起止页码：1422-1426

外文期刊名：ADVANCED SYNTHESIS & CATALYSIS

收录：;Scopus(收录号：2-s2.0-85127302657);WOS:【SCI-EXPANDED(收录号:WOS:000772890900001)，CCR-EXPANDED(收录号:WOS:000772890900001)】；

基金：We gratefully acknowledge financial support from the National Natural Science Foundation of China (21801214), Natural Science Foundation of Henan (202300410016) and the University Student Innovation Program of Henan Province (202111071021).

语种：英文

外文关键词：1,3,5-triazines; diazo compounds; tertbutyl nitrite; metal-free; three-component reaction

摘要：A procedure for the transition-metal-free three-component reaction of 1,3,5-triazines, diazo compounds and tert-butyl nitrite has been described. This reaction goes through tandem nucleophilic attack to generate synthetically important beta-aminonitroso-alpha-diazocarbonyl compounds in moderate to good yields. This protocol is distinguished by the use of readily available starting materials, wide substrate scope and operational simplicity. Notably, a N-N bond and a C-C bond were formed simultaneously.