文献类型：期刊文献

英文题名：Syntheses of two coordination polymers with rutile-type topology and the single-crystal-to-single-crystal transformation of Mg(II) complex induced by methanol

作者：He, Yuan-Chun[1];Guo, Jiao[2];Zhang, Hong-Mei[1];Yang, Jin[1];Liu, Ying-Ying[1];Ma, Jian-Fang[1]

第一作者：He, Yuan-Chun

通讯作者：He, YC[1]

机构：[1]NE Normal Univ, Dept Chem, Key Lab Polyoxometalate Sci, Changchun 130024, Peoples R China;[2]Xinxiang Univ, Coll Chem & Chem Engn, Xinxiang 453003, Henan, Peoples R China

第一机构：NE Normal Univ, Dept Chem, Key Lab Polyoxometalate Sci, Changchun 130024, Peoples R China

通讯机构：[1]corresponding author), NE Normal Univ, Dept Chem, Key Lab Polyoxometalate Sci, Changchun 130024, Peoples R China.

年份：2014

卷号：16

期号：20

起止页码：4210-4214

外文期刊名：CRYSTENGCOMM

收录：;Scopus(收录号：2-s2.0-84899477279);WOS:【SCI-EXPANDED(收录号:WOS:000335817500020)】；

基金：This work was supported by the National Natural Science Foundation of China (grant no. 21071028, 21001023, 21277022, 21371030, 21301026) and the Fundamental Research Funds for the Central Universities of China.

语种：英文

摘要：Two isomorphous 3D frameworks with rutile topology based on isonicotinate, [Mn(IN)(2)]center dot H2O (1) and [Mg(IN)(2)]center dot H2O (2), were prepared. Compound 1 shows excellent stability in alcohols, while compound 2 reveals a rare single-crystal-to-single-crystal transformation from a 3D structure to a mononuclear molecule of [Mg(IN)(2)(CH3OH)(4)] (3) by soaking in methanol.