文献类型：期刊文献

英文题名：Co-Catalyzed Oxidative Alkylation between Styrenes and Cyclic Ethers via sp3 C-H Functionalization

作者：Chen, Rongxiang[1];Wang, Kai-Kai[1];Wang, Zhan-Yong[1];Ma, Xueji[1];Wang, Doudou[1];Zhang, An-an[2];Liu, Lantao[2]

第一作者：Chen, Rongxiang

通讯作者：Chen, RX[1];Liu, LT[2]

机构：[1]Xinxiang Univ, Coll Chem & Chem Engn, Xinxiang 453000, Henan, Peoples R China;[2]Shangqiu Normal Univ, Coll Chem & Chem Engn, Shangqiu 476000, Henan, Peoples R China

第一机构：新乡学院化学化工学院

通讯机构：[1]corresponding author), Xinxiang Univ, Coll Chem & Chem Engn, Xinxiang 453000, Henan, Peoples R China;[2]corresponding author), Shangqiu Normal Univ, Coll Chem & Chem Engn, Shangqiu 476000, Henan, Peoples R China.|[110713]新乡学院化学化工学院;[11071]新乡学院;

年份：2020

卷号：5

期号：6

起止页码：2078-2081

外文期刊名：CHEMISTRYSELECT

收录：;Scopus(收录号：2-s2.0-85079700379);WOS:【SCI-EXPANDED(收录号:WOS:000513245800038)】；

基金：We gratefully acknowledge financial support from the National Natural Science Foundation of China (21801214, 21572126), and the Higher Education Institution Key Research Project Plan of Henan Province of China (20B150019).

语种：英文

外文关键词：Co-catalytic; Cyclic ether; Oxidative alkylation; Styrenes; sp3 C-H functionalization

摘要：A new cobalt-catalyzed oxidative alkylation from readily available styrenes and ethers has been disclosed for a rapid and highly efficient construction of C-C bond via sp3 C-H bond functionalization. Various substituted styrenes and cyclic ethers are well investigated and give satisfactory results. Preliminary mechanism studies suggested that this transformation may involve a radical process. This methodology was demonstrated by good yields and functional group compatibility with simple operation, easily available starting materials and low catalyst loadings.