文献类型：期刊文献

英文题名：Bis(imidazole) Cation Templates and Subtle Effect: Syntheses and Characterization of Three New Pb(II) Halide Supramolecular Polymers

作者：Wang, Chao-Hai[1,2];Ma, Cheng-Jie[1,2];Huang, Zhi-Peng[1,2];Zai, Yu-Xia[1,2];Yang, Qing[1,2];Li, Li[1,2];Liang, Yu[1,2];Niu, Yun-Yin[1,2]

第一作者：Wang, Chao-Hai

通讯作者：Liang, Y[1]

机构：[1]Zhengzhou Univ, Coll Chem & Mol Engn, Zhengzhou 450001, Peoples R China;[2]Xinxiang Univ, Coll Chem & Chem Engn, Xinxiang 453000, Peoples R China

第一机构：Zhengzhou Univ, Coll Chem & Mol Engn, Zhengzhou 450001, Peoples R China

通讯机构：[1]corresponding author), Xinxiang Univ, Coll Chem & Chem Engn, Xinxiang 453000, Peoples R China.|[110713]新乡学院化学化工学院;[11071]新乡学院;

年份：2015

卷号：26

期号：4

起止页码：1027-1039

外文期刊名：JOURNAL OF CLUSTER SCIENCE

收录：;Scopus(收录号：2-s2.0-84934436660);WOS:【SCI-EXPANDED(收录号:WOS:000357120700001)】；

基金：Research efforts in the Niu group are supported by the National Science Foundation of China (No. 21171148, J1103309). Foundation and Frontier Research Project of Henna Province (No. 132300410265) and Xinxiang Science and Technology Key projects Fund (ZG13012).

语种：英文

外文关键词：Cation templates; Methylimidazolium; Inorganic/organic interactions

摘要：Three novel cation-templated complexes, {(dmb)[Pb2Cl2I4]}(n) (1), {(ddb) [Pb2I6]}(n) (2), {(dmh)[Pb2I6]}(n) (3) (dmb = alpha,alpha-di(3-methylimidozole-1-yl) benzene dichloride, ddb = alpha,alpha-di(2,3-dimethylimidozole-1-yl) benzene dichloride, dmh = 1,6-di(3-methylimidozole) hexane have been synthesized via the self-assembly reaction in solution. The X-ray crystallography shows these compounds were all composed of imidazole organic dications and halocluster anions. It is the H-bonds and electrostatic interactions between the organic counteractions and inorganic moieties that do the contribution to the crystal packing. These compounds have been further characterized by IR spectroscopy, UV-Vis spectra and thermostability properties.