文献类型：期刊文献

英文题名：Synthesis and Crystal Structure of A New Co(II) Coordination Polymer With a Rare Two-Fold bbg Topology

作者：Yao, Peng[1]

第一作者：姚鹏

通讯作者：Yao, P[1]

机构：[1]Xinxiang Univ, Dept Chem & Chem Engn, Xinxiang 453003, Henan, Peoples R China

第一机构：新乡学院化学化工学院

通讯机构：[1]corresponding author), Xinxiang Univ, Dept Chem & Chem Engn, Xinxiang 453003, Henan, Peoples R China.|[110713]新乡学院化学化工学院;[11071]新乡学院;

年份：2015

卷号：45

期号：10

起止页码：1470-1473

外文期刊名：SYNTHESIS AND REACTIVITY IN INORGANIC METAL-ORGANIC AND NANO-METAL CHEMISTRY

收录：;Scopus(收录号：2-s2.0-84930196828);WOS:【SCI-EXPANDED(收录号:WOS:000371321600005)】；

语种：英文

外文关键词：coordination polymer; Co(II); crystal structure

摘要：A new Co (II) coordination polymer with 1,3-di(3,5-dicarboxylphenyl) benzene (H(4)ddb) and 1,4-bis(imidazol-1-yl) benzene (bib) has been prepared by hydrothermal synthesis and characterized by single-crystal X-ray diffraction, IR, and EA. Complex, [Co-2(ddb) (bib)(2) (H2O)(2)](n) (1), is monoclinic, space group C2/c with a = 25.903 (5), b = 10.316 (5), c = 19.680 (5) angstrom, beta = 128.191(5)degrees, V = 4133 (2) angstrom(3), Z = 8, Mr = 487.33, D-c = 1.566 g/cm(3), F(000) = 1992, and mu = 0.88 mm(1). The final refinement gave R = 0.0326 and wR = 0.0781 for 3716 reflections with I > 2 sigma(I). X-ray diffraction analysis reveals that the complex 1 displays a two-fold three-dimensional structure with (4,4)-connected bbg topology.