文献类型：期刊文献

英文题名：catena-Poly[[[ diaquacopper(II)]-bis[mu-1,5-bis (1H-imidazol-1-yl)pentane-kappa N-2(3):N-3']] naphthalene-1,5-disulfonate]

作者：Zhang, Lai-Ping[1];Wen, Shu-Tang[1];Fu, Xiao-Ning[1]

第一作者：张来苹

通讯作者：Zhang, LP[1]

机构：[1]Xinxiang Univ, Dept Chem & Chem Engn, Xinxiang 453000, Peoples R China

第一机构：新乡学院化学化工学院

通讯机构：[1]corresponding author), Xinxiang Univ, Dept Chem & Chem Engn, Xinxiang 453000, Peoples R China.|[110713]新乡学院化学化工学院;[11071]新乡学院;

年份：2012

卷号：68

起止页码：M1505-+

外文期刊名：ACTA CRYSTALLOGRAPHICA SECTION E-CRYSTALLOGRAPHIC COMMUNICATIONS

收录：WOS:【ESCI(收录号:WOS:000421563200056)】；

基金：We thank the Science and Technology Key Projects for Technological Research on Preparation and Application of TiO2, Henan Province (grant No. 0624270006), for support.

语种：英文

摘要：In the title complex, {[Cu(C11H16N4)(2)(H2O)(2)](C10H6O6S2)}n, the Cu-II atom, lying on an inversion center, is six-coordinated by two water molecules and four N atoms from four 1,5bis(1H-imidazol-1-yl)pentane (biim-5) ligands in a distorted octahedral geometry. Adjacent Cu-II atoms are linked by two biim-5 ligands, forming a chain along [111]. Two atoms of the pentane group are disordered over two sets of sites, with an occupancy ratio of 0.554 (18):0.446 (18). Intermolecular O-H center dot center dot center dot O hydrogen bonds link the chains and the centrosymmetric naphthalene-1,5-disulfonate anions into a layer structure parallel to (0 (1) over bar1).