文献类型：期刊文献

中文题名：梳状聚合物PAALi-g-PEO的合成与表征

英文题名：Sythesis and characterization of comb-shaped copolymer PAALi-g-PEO

作者：陈磊山[1];胡利强[1];郭晓伟[1];文书堂[1]

机构：[1]新乡学院化学与化工学院

第一机构：新乡学院化学化工学院

年份：2013

卷号：35

期号：3

起止页码：285-288

中文期刊名：化学试剂

外文期刊名：Chemical Reagents

收录：CSTPCD;;北大核心:【北大核心2011】；CSCD:【CSCD_E2013_2014】；

语种：中文

中文关键词：大分子单体法;梳状聚合物;PAALi—g—PEO;聚合物电解质

外文关键词：macromonomer method ; comb-shaped copolymer; PAALi-g-PEO ; polymer electrolyte

摘要：采用大分子单体法设计并合成出非晶态的标题化合物,利用红外光谱和核磁共振氢谱对产物进行结构表征,利用差示扫描量热法(DSC)测定产物的玻璃化转变温度(Tg)和结晶度,并研究了原料和配比对产物的影响。结果表明,所合成的梳状共聚物PAALi-g-PEO为非晶态,其Tg在-54℃左右;当以MPEG-600为原料,EO/AALi=4时,产物适宜作为聚合物电解质基体。
The comb-shaped copolymer PAALi-g-PEO was de- signed and synthesized by macromonomer method. The structure of the products were characterized by infra-red spectra （IR） and proton nuclear magnetic resonance spectra （1HNMR）. The glass transition temperature（ Tg） and crystal-linity were determined by differential scanning calorimetry （DSC）. The effect of raw materials and molar ratio on the products were investigated. The results show that the comb- shaped copolymer PAALi-g-PEO synthesized by macromonomer method is amorphous with a glass transition temperature about -54℃. When taking MPEG-600 as raw material with the molar ratio of EO/AALi at PAALi-g-PEO is more suitable trolyte. 4, the comb-shaped eopolymer to be a matrix of polymer elec-trolyte.