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A New Cd(II) Coordination Polymer with a Rare tfz-d Topology Constructed by Asymmetrically Tricarboxylate and Imidazole-Containing Ligand: Synthesis, Crystal structure and Luminescent Property  ( SCI-EXPANDED收录 EI收录)  

文献类型:期刊文献

英文题名:A New Cd(II) Coordination Polymer with a Rare tfz-d Topology Constructed by Asymmetrically Tricarboxylate and Imidazole-Containing Ligand: Synthesis, Crystal structure and Luminescent Property

作者:Yao, Peng[1]

第一作者:姚鹏

通讯作者:Yao, P[1]

机构:[1]Xinxiang Univ, Dept Chem & Chem Engn, Xinxiang 453003, Henan, Peoples R China

第一机构:新乡学院化学化工学院

通讯机构:[1]corresponding author), Xinxiang Univ, Dept Chem & Chem Engn, Xinxiang 453003, Henan, Peoples R China.|[110713]新乡学院化学化工学院;[11071]新乡学院;

年份:2014

卷号:24

期号:3

起止页码:568-572

外文期刊名:JOURNAL OF INORGANIC AND ORGANOMETALLIC POLYMERS AND MATERIALS

收录:;EI(收录号:20141617594494);Scopus(收录号:2-s2.0-84898548096);WOS:【SCI-EXPANDED(收录号:WOS:000334427200011)】;

语种:英文

外文关键词:Crystal structure; Cd(II); Luminescent property

摘要:A new coordination polymer [Cd(Hbtc)(bib)(0.5)] (n) (1) (H(3)btc = biphenyl-3,4',5-tricarboxylate and bib = 1,4-bis(imidazol-1-yl)benzene) has been obtained under hydrothermal conditions. The structure of complex 1 has been determined by single-crystal X-ray diffraction analysis and further characterized by elemental analysis and IR spectrum. The complex 1 shows a (3,8)-connected twofold interpenetrated three-dimensional (3D) tfz-d topology with the point symbol (4(3))(2) (4(6)center dot 6(18)center dot 8(4)). The photoluminescence behavior of complex 1 was also discussed in paper.

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