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ZnIn2S4 nanopowder as an efficient visible light-driven photocatalyst in the reduction of aqueous Cr(VI)  ( SCI-EXPANDED收录 EI收录)  

文献类型:期刊文献

英文题名:ZnIn2S4 nanopowder as an efficient visible light-driven photocatalyst in the reduction of aqueous Cr(VI)

作者:Wang, Tian Xi[1];Xu, Shao Hong[2];Yang, Feng Xia[1]

第一作者:Wang, Tian Xi

通讯作者:Wang, TX[1]

机构:[1]Henan Inst Sci & Technol, Sch Chem & Chem Engn, Xinxiang 453003, Peoples R China;[2]Xinxiang Univ, Dept Chem & Chem Engn, Xinxiang 453000, Peoples R China

第一机构:Henan Inst Sci & Technol, Sch Chem & Chem Engn, Xinxiang 453003, Peoples R China

通讯机构:[1]corresponding author), Henan Inst Sci & Technol, Sch Chem & Chem Engn, Xinxiang 453003, Peoples R China.

年份:2012

卷号:83

起止页码:46-48

外文期刊名:MATERIALS LETTERS

收录:;EI(收录号:20123015283626);Scopus(收录号:2-s2.0-84864147203);WOS:【SCI-EXPANDED(收录号:WOS:000308118500014)】;

语种:英文

外文关键词:Semiconductors; Nanocrystalline materials; Photocatalysis; XPS

摘要:ZnIn2S4 nanopowder was synthesized via a facile hydrothermal method using Zn(CH3COO)(2)center dot 2H(2)O, InCl3 center dot 4H(2)O and thioacetamide as the reactants, and characterized by X-ray diffraction, transmission electron microscopy. N-2 adsorption and UV-Vis diffuse reflectance spectrum. The photocatalytic property of the as-synthesized ZnIn2S4 nanopowder was tested for the first time by the reduction of aqueous Cr(VI) under visible light (lambda>420 nm) irradiation, and compared with those of In2S3, ZnS and P25 TiO2. It was found that the as-synthesized ZnIn2S4 nanopowder was much more efficient than In2S3. ZnS and P25 TiO2 in the photocatalytic reduction of aqueous Cr(VI). Moreover, X-ray photoelectron spectroscopy analysis revealed that Cr(VI) was reduced to Cr(III) by ZnIn2S4-mediated photocatalysis. (C) 2012 Elsevier B.V. All rights reserved.

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