文献类型：期刊文献

英文题名：Unexpected ester and phosphonate radical generation by hypervalent iodine compounds for synthesizing 6-phenanthridine derivatives

作者：Ma, Xueji[1];Sun, Aili[1];Wang, Kai-Kai[1]

通讯作者：Sun, AL[1];Wang, KK[1]

机构：[1]Xinxiang Univ, Sch Pharm, Key Lab Nanocarbon Modified Film Technol Engn Hen, Xinxiang 453000, Henan, Peoples R China

第一机构：新乡学院

通讯机构：[1]corresponding author), Xinxiang Univ, Sch Pharm, Key Lab Nanocarbon Modified Film Technol Engn Hen, Xinxiang 453000, Henan, Peoples R China.|[11071]新乡学院;

年份：2022

卷号：46

期号：15

起止页码：6856-6859

外文期刊名：NEW JOURNAL OF CHEMISTRY

收录：;EI(收录号：20221611988008);Scopus(收录号：2-s2.0-85128424039);WOS:【SCI-EXPANDED(收录号:WOS:000776781400001)，CCR-EXPANDED(收录号:WOS:000776781400001)】；

基金：The authors gratefully acknowledge the financial support from the NSFC (21702176 and 21801214).

语种：英文

外文关键词：Carboxylation - Positive ions

摘要：An unprecedented elimination of diazomethane process of a diazo group-bearing hypervalent iodine reagent has been described. This process provides ester and phosphonate radicals, which can react with 2-isocyanobiaryls to afford phenanthridine-6-carboxylate/phosphonate derivatives in moderate to good yields.