文献类型：期刊文献

英文题名：A water-promoted catalytic hydrodecarboxylation of conjugated carboxylic acids under open air conditions at room temperature

作者：Wang, Zhan-Yong[1];Yang, Ting[2];Wang, Kai-Kai[1];Liu, Dong-Fang[3];Ma, Xueji[1];Wang, Nan[1];Liu, Hong[1];Sun, Aili[1];Liu, Hongxin[4,5]

通讯作者：Liu, HX[1];Liu, HX[2]

机构：[1]Xinxiang Univ, Sch Pharm, Xinxiang 453003, Peoples R China;[2]Xinxiang Univ, Nursing Coll, Xinxiang 453003, Peoples R China;[3]Xinxiang Runyu Mat Co Ltd, Xinxiang 453003, Peoples R China;[4]Wenzhou Univ, Coll Chem & Mat Engn, Wenzhou, Peoples R China;[5]Wenzhou Univ, Inst New Mat & Ind Technol, Wenzhou, Peoples R China

第一机构：新乡学院

通讯机构：[1]corresponding author), Wenzhou Univ, Coll Chem & Mat Engn, Wenzhou, Peoples R China;[2]corresponding author), Wenzhou Univ, Inst New Mat & Ind Technol, Wenzhou, Peoples R China.

年份：0

外文期刊名：GREEN CHEMISTRY

收录：;EI(收录号：20231714023733);Scopus(收录号：2-s2.0-85153627788);WOS:【SCI-EXPANDED(收录号:WOS:000969228800001)，CCR-EXPANDED(收录号:WOS:000969228800001)】；

基金：We gratefully acknowledge the NSFC (21702176), the Higher Education Institution Key Research Project Plan of Henan Province of China (22B150015), the Foundation of Wenzhou Basic Scientific Research Project (G20220002), the Foundation of 2021 Wenzhou Association for Science and Technology Service Innovation Project (kjfw35) and the Foundation of Zhejiang Educational Committee (Y201839490) for financial support.

语种：英文

摘要：A water-promoted DABCO-organocatalyzed hydrodecarboxylation of conjugated carboxylic acids has been developed, providing the corresponding decarboxylation products in good to excellent yields. This metal-, photocatalyst-, and oxidant-free protocol features high functional group tolerance, wide substrate scope, gram-scale synthesis, and operational simplicity under open air conditions at room temperature. A trace amount of water as the hydrogen source for the successful conversion and the origin of the chemoselectivity are demonstrated through a series of control experiments.