文献类型：期刊文献

英文题名：3D Supramolecular Structure Assembled by Hydrogen Bonding Interaction with InS Topology

作者：Yao, Peng[1]

第一作者：姚鹏

通讯作者：Yao, P[1]

机构：[1]Xinxiang Univ, Dept Chem & Chem Engn, Xinxiang 453003, Henan, Peoples R China

第一机构：新乡学院化学化工学院

通讯机构：[1]corresponding author), Xinxiang Univ, Dept Chem & Chem Engn, Xinxiang 453003, Henan, Peoples R China.|[110713]新乡学院化学化工学院;[11071]新乡学院;

年份：2015

卷号：45

期号：10

起止页码：1467-1469

外文期刊名：SYNTHESIS AND REACTIVITY IN INORGANIC METAL-ORGANIC AND NANO-METAL CHEMISTRY

收录：;Scopus(收录号：2-s2.0-84930226219);WOS:【SCI-EXPANDED(收录号:WOS:000371321600004)】；

语种：英文

外文关键词：coordination polymer; InS topology; nickel(II)

摘要：A new coordination polymer [Ni(L)(bib)](n) (H(2)LD5-hydroxyisophthalic acid, bibD1,4-bis (2-methyl-imidazol-1-yl) butane) has been prepared by hydrothermal synthesis and characterized by single-crystal X-ray diffraction, IR, and elemental analysis. The crystal is of monoclinic, space group P2(1)/n with a = 8.949(4), b = 20.620(9), c = 10.945(5) angstrom, beta = 103.642(5)degrees, C-20 H-22 N-4 NiO5. M-r = 457.11, V = 1962.7(15) angstrom(3), D-c = 1.547 g/cm(3), F(000) = 952, mu = 1.030 mm, and Z = 4. The final refinement gave R = 0.0244 and wR = 0.0654 for 3227 reflections with I > 2 sigma(I). The analytic conclusions reveal that the carboxylate groups adopt chelating coordination mode, which lead to form a 1D chain. The 1D chain is further connected by the bib ligand to form 2D layer. Through hydrogen bonding interactions, the 3D supramolecular structure is formed with InS topology.