文献类型：期刊文献

英文题名：Visible-Light Photocatalytic Reduction of Aryl Halides as a Source of Aryl Radicals

作者：Lan, Jihong[1];Chen, Rongxiang[2];Duo, Fangfang[1];Hu, Menghui[1];Lu, Xiaoyan[3]

通讯作者：Lan, JH[1];Lu, XY[2]

机构：[1]Xinxiang Univ, Sch Chem & Mat Engn, Xinxiang 453003, Henan, Peoples R China;[2]Xinxiang Univ, Sch Pharm, Xinxiang 453003, Henan, Peoples R China;[3]Luoyang Normal Univ, Coll Chem & Chem Engn, Luoyang 471934, Peoples R China

第一机构：新乡学院

通讯机构：[1]corresponding author), Xinxiang Univ, Sch Chem & Mat Engn, Xinxiang 453003, Henan, Peoples R China;[2]corresponding author), Luoyang Normal Univ, Coll Chem & Chem Engn, Luoyang 471934, Peoples R China.|[11071]新乡学院;

年份：2022

卷号：27

期号：17

外文期刊名：MOLECULES

收录：;Scopus(收录号：2-s2.0-85137546124);WOS:【SCI-EXPANDED(收录号:WOS:000851768400001)】；

基金：This research was funded by Key Scientific Research Projects of Higher Education of He'nan Province (Grant 22A150016).

语种：英文

外文关键词：visible light; aryl halides; photoinduced electron transfer; reduction; aryl radicals

摘要：Aryl- and heteroaryl units are present in a wide variety of natural products, pharmaceuticals, and functional materials. The method for reduction of aryl halides with ubiquitous distribution is highly sought after for late-stage construction of various aromatic compounds. The visible-light-driven reduction of aryl halides to aryl radicals by electron transfer provides an efficient, simple, and environmentally friendly method for the construction of aromatic compounds. This review summarizes the recent progress in the generation of aryl radicals by visible-light-driven reduction of aryl halides with metal complexes, organic compounds, semiconductors as catalysts, and alkali-assisted reaction system. The ability and mechanism of reduction of aromatic halides in various visible light induced systems are summarized, intending to illustrate a comprehensive introduction of this research topic to the readers.