文献类型：期刊文献

英文题名：Synthesis, Structures and Photocatalytic Properties of Two Novel Ag(I) Polymers Directed by 1,3-Bis(4-methylpyridine)alkane Cation

作者：Liu, Mei[1];Liang, Yu[2];Wang, Chao-Hai[3];Ma, Cheng-Jie[3];Niu, Yun-Yin[3]

第一作者：Liu, Mei

通讯作者：Niu, YY[1]

机构：[1]Henan Jiaozuo Teachers Coll, Phys Chem & Biol Dept, Jiaozuo 454000, Peoples R China;[2]Xinxiang Univ, Coll Chem & Chem Engn, Xinxiang 453000, Peoples R China;[3]Zhengzhou Univ, Coll Chem & Mol Engn, Zhengzhou 450001, Peoples R China

第一机构：Henan Jiaozuo Teachers Coll, Phys Chem & Biol Dept, Jiaozuo 454000, Peoples R China

通讯机构：[1]corresponding author), Zhengzhou Univ, Coll Chem & Mol Engn, Zhengzhou 450001, Peoples R China.

年份：2015

卷号：26

期号：5

起止页码：1723-1733

外文期刊名：JOURNAL OF CLUSTER SCIENCE

收录：;Scopus(收录号：2-s2.0-84939775150);WOS:【SCI-EXPANDED(收录号:WOS:000360224300025)】；

基金：Research efforts in the Niu group are supported by the National Science Foundation of China (Nos. 21171148, J1103309). Foundation and Frontier Research Project of Henna Province (No. 132300410265) and Xinxiang Science and Technology Key Projects Fund (ZG13012).

语种：英文

外文关键词：Cation templates; Photocatalytic; Self-assembly

摘要：Cation-templated self-assembly of 1,3-bis(4-methylpyridine)alkane cation with AgBr or AgI was studied and two new complexes were obtained: {(bmpp)[Ag2Br4]}(n) (1) and {(bmpp)[Ag4I6]}(n) (2) [bmpp = 1,3-bis(4-methylpyridine)alkane cation]. Compounds 1-2 were characterized by elemental analysis, IR, TG, and X-ray crystallography. The two compounds have 1D chain structure. Furthermore, photocatalytic properties at ambient temperature were also investigated. We report two new extend supramolecular polymers based on Ag(I) and 1,3-bis(4-methylpyridine)alkane cation. Compounds 1-2 have 1D chain structures. Furthermore, photocatalytic properties at ambient temperature were also investigated.