文献类型：期刊文献

英文题名：Mesoporous Sn(IV) Doping DFNS Supported BaMnO(3)Nanoparticles for Formylation of Amines Using Carbon Dioxide

作者：Yang, Jie[1];Wang, Liujie[1];Sun, Aili[2];Zhiani, Rahele[3]

第一作者：杨杰

通讯作者：Sun, AL[1];Zhiani, R[2]

机构：[1]Xinxiang Univ, Coll Chem & Chem Engn, Xinxiang 453003, Henan, Peoples R China;[2]Xinxiang Univ, Henan Engn Lab Nanocarbon Modificat Membrane Tech, Xinxiang 453003, Henan, Peoples R China;[3]Islamic Azad Univ, Neyshabur Branch, Fac Sci, Dept Chem, Neyshabur, Iran

第一机构：新乡学院化学化工学院

通讯机构：[1]corresponding author), Xinxiang Univ, Henan Engn Lab Nanocarbon Modificat Membrane Tech, Xinxiang 453003, Henan, Peoples R China;[2]corresponding author), Islamic Azad Univ, Neyshabur Branch, Fac Sci, Dept Chem, Neyshabur, Iran.|[11071]新乡学院;

年份：2021

卷号：151

期号：2

起止页码：573-581

外文期刊名：CATALYSIS LETTERS

收录：;WOS:【SCI-EXPANDED(收录号:WOS:000551370700001)，CCR-EXPANDED(收录号:WOS:000551370700001)】；

基金：This work was financially supported by the National Natural Science Foundation of China (Grant No.: 51701173) and the Key Scientific and Technological Research Project of Henan Province (Grant No.: 202102310298).

语种：英文

外文关键词：Nano catalyst; BaMnO3; N-formylation; Green chemistry; CO2

摘要：In the present paper, Sn(IV) doping DFNS (SnD) supported nanoparticles of BaMnO3(BaMnO3/SnD) and using as a catalyst for theN-formylation of amines by CO(2)hydrogenation. In this catalyst, the SnD with the ratios of Si/Sn in the range of from 6 to 50 were obtained with method of direct hydrothermal synthesis (DHS) as well as the nanoparticles of BaMnO(3)were on the surfaces of SnD in situ reduced. Scanning electron microscope (SEM), X-ray diffraction (XRD), Fourier transform infrared spectroscopy (FT-IR), X-ray energy dispersive spectroscopy (EDS), and transmission electron microscopy (TEM) were utilized for characterizing the nanostructures BaMnO3/SnD. It is found that the nanostructures of BaMnO3/SnD can be a nominate due to its effective and novel catalytic behavior inN-formylation of amines through hydrogenation of CO2. [GRAPHICS] .