文献类型：期刊文献

英文题名：Syntheses and Crystal Structures of Three Supramolecular Halides: (DDTD)[Zn(N-3)(3)Cl], (DDTD)[Hg2Br6], (DDTD)[Cd-4(N-3)(6)(Cl)(8)] Directed by DDTD Dication

作者：Liang, Yu[1];Yue, Zhong-Cheng[2];Li, Li[2];Guo, Xiao-Ling[2]

第一作者：梁宇

通讯作者：Liang, Y[1]

机构：[1]Xinxiang Univ, Coll Chem & Chem Engn, Xinxiang 453000, Peoples R China;[2]Zhengzhou Univ, Coll Chem & Mol Engn, Zhengzhou, Peoples R China

第一机构：新乡学院化学化工学院

通讯机构：[1]corresponding author), Xinxiang Univ, Coll Chem & Chem Engn, Xinxiang 453000, Peoples R China.|[110713]新乡学院化学化工学院;[11071]新乡学院;

年份：2013

卷号：43

期号：1

起止页码：90-95

外文期刊名：SYNTHESIS AND REACTIVITY IN INORGANIC METAL-ORGANIC AND NANO-METAL CHEMISTRY

收录：;Scopus(收录号：2-s2.0-84871230837);WOS:【SCI-EXPANDED(收录号:WOS:000322305700015)】；

语种：英文

外文关键词：5, 8-Diazoniadispiro[4.2.4.2] tetradecane; crystal structure; self-assembly reaction

摘要：The self-assembly reaction of metal halides with DDTD dication (DDTD = 5,8 -Diazoniadispiro[4.2.4.2] tetradecane) yielded three novel organic-inorganic hybrid mental halides (DDTD)[Zn(N-3)(3)Cl] (1), (DDTD)[Hg2Br6] (2), and (DDTD)[Cd-4(N-3)(6)(Cl)(8)] (3), which are characterized by X-ray crystallography and IR spectroscopy. The crystal structures of 1-3 show that they all crystallize in monoclinic systems. Compound 1 is mononuclear complex, compound 2 is binuclear complex, and compound 3 is a tetranuclear polymer. These compounds contained a variety of inorganic frameworks, due to the different coordinated modes of metal centers with halogen, which accordingly led to the change of the C-H center dot center dot center dot Cl(Br) interactions in the complexes.