文献类型：期刊文献

英文题名：Syntheses, Crystal Structures, UV-Vis Absorption, and Fluorescent Properties of a Complex: [btx][Cu2I4]

作者：Du, Hai-Juan[1];Liang, Yu[2];Wang, Ling-Fang[1];Niu, Yun-Yin[1]

第一作者：Du, Hai-Juan

通讯作者：Niu, YY[1]

机构：[1]Zhengzhou Univ, Dept Chem, Zhengzhou 450052, Peoples R China;[2]Xinxiang Univ, Coll Chem & Chem Engn, Xinxiang, Peoples R China

第一机构：Zhengzhou Univ, Dept Chem, Zhengzhou 450052, Peoples R China

通讯机构：[1]corresponding author), Zhengzhou Univ, Dept Chem, Zhengzhou 450052, Peoples R China.

年份：2012

卷号：42

期号：3

起止页码：364-368

外文期刊名：SYNTHESIS AND REACTIVITY IN INORGANIC METAL-ORGANIC AND NANO-METAL CHEMISTRY

收录：;Scopus(收录号：2-s2.0-84860446510);WOS:【SCI-EXPANDED(收录号:WOS:000303589900011)】；

基金：The authors gratefully acknowledge the financial support of The National Science Foundation of China (No. 20671083).

语种：英文

外文关键词：binuclear coordination compound; organoammonium cations; photoluminescent properties; self-assembly; UV-vis absorption spectra

摘要：The self-assembly reaction of organic cation and metal iodides yielded a novel binuclear coordination compound, namely [btx][Cu2I4](1) [btx = 1,6-bis(triethylmethylammonium)xylol], which is characterized by X-ray crystallography, IR spectroscopy, fluorescence spectra, and UV-vis absorption spectra. The compound 1 crystallizes in Monoclinic, space group P2(1)/c with a = 8.2246(12), b = 11.5843(17), c = 15.005(2), alpha = 90 degrees, beta = 94.218(2)degrees, gamma = 90 degrees. In the anion [Cu2I4](2-), each Cu center is triangularly coordinated by two mu(2)-I(2) atoms and one terminal I(1) atom. The organic cationic [btx](2+) existed around it through supramolecular interactions.