文献类型：期刊文献

英文题名：Mesoporous Sn(IV) Doping DFNS Supported BaMnO3 Nanoparticles for Formylation of Amines Using Carbon Dioxide

作者：Yang, Jie[1]; Wang, Liujie[1]; Sun, Aili[2]; Zhiani, Rahele[3]

第一作者：杨杰

通讯作者：Sun, Aili

机构：[1] College of Chemistry and Chemical Engineering, Xinxiang University, Xinxiang, Henan, 453003, China; [2] Henan Engineering Laboratory of Nano-carbon Modification Membrane Technology, Xinxiang University, Xinxiang, Henan, 453003, China; [3] Department of Chemistry, Faculty of Sciences, Neyshabur Branch, Islamic Azad University, Neyshabur, Iran

第一机构：新乡学院化学化工学院

通讯机构：[3]Department of Chemistry, Faculty of Sciences, Neyshabur Branch, Islamic Azad University, Neyshabur, Iran

年份：2021

卷号：151

期号：2

起止页码：573-581

外文期刊名：Catalysis Letters

收录：EI(收录号：20203008976373);Scopus(收录号：2-s2.0-85088398037)

语种：英文

外文关键词：Energy dispersive spectroscopy - Silicon - Carbon dioxide - Fourier transform infrared spectroscopy - High resolution transmission electron microscopy - Hydrothermal synthesis - Nanoparticles - Amines - Hydrogenation - Nanocatalysts - Scanning electron microscopy - Tin compounds

摘要：Abstract: In the present paper, Sn(IV) doping DFNS (SnD) supported nanoparticles of BaMnO3 (BaMnO3/SnD) and using as a catalyst for the N-formylation of amines by CO2 hydrogenation. In this catalyst, the SnD with the ratios of Si/Sn in the range of from 6 to 50 were obtained with method of direct hydrothermal synthesis (DHS) as well as the nanoparticles of BaMnO3 were on the surfaces of SnD in situ reduced. Scanning electron microscope (SEM), X-ray diffraction (XRD), Fourier transform infrared spectroscopy (FT-IR), X-ray energy dispersive spectroscopy (EDS), and transmission electron microscopy (TEM) were utilized for characterizing the nanostructures BaMnO3/SnD. It is found that the nanostructures of BaMnO3/SnD can be a nominate due to its effective and novel catalytic behavior in N-formylation of amines through hydrogenation of CO2. Graphic Abstract: [Figure not available: see fulltext.] ? 2020, Springer Science+Business Media, LLC, part of Springer Nature.