文献类型：期刊文献

英文题名：Heterometallic Cluster Coordination Polymers Assembled from Cuprous-Halide Clusters and Organotin-Oxygen Pyridinecarboxylate Clusters

作者：Li, Lan-Yun[1];Duan, Guang-Xiong[1];Liu, Jing-Yan[1];Zhang, Lai-Ping[2];Xie, Yun-Peng[1];Lu, Xing[1]

第一作者：Li, Lan-Yun

通讯作者：Xie, YP[1]

机构：[1]Huazhong Univ Sci & Technol HUST, Sch Mat Sci & Engn, State Key Lab Mat Proc & Die & Mould Technol, Wuhan 430074, Peoples R China;[2]Xinxiang Univ, Coll Chem & Chem Engn, Xinxiang 453000, Henan, Peoples R China

第一机构：Huazhong Univ Sci & Technol HUST, Sch Mat Sci & Engn, State Key Lab Mat Proc & Die & Mould Technol, Wuhan 430074, Peoples R China

通讯机构：[1]corresponding author), Huazhong Univ Sci & Technol HUST, Sch Mat Sci & Engn, State Key Lab Mat Proc & Die & Mould Technol, Wuhan 430074, Peoples R China.

年份：2020

卷号：20

期号：6

起止页码：3795-3800

外文期刊名：CRYSTAL GROWTH & DESIGN

收录：;EI(收录号：20202808929082);Scopus(收录号：2-s2.0-85087707914);WOS:【SCI-EXPANDED(收录号:WOS:000538515500026)】；

基金：We gratefully acknowledge financial support by National Natural Science Foundation of China (Nos. 21771071, 51672093, and 51472095). We thank the staff in the BL17B beamline of the National Center for Protein Sciences Shanghai (NCPSS) at Shanghai Synchrotron Radiation Facility for the assistance with data collection and the Analytical and Testing Center at the Huazhong University of Science and Technology for Elemental analyses.

语种：英文

外文关键词：Carboxylation - Organometallics - Oxygen - Polymers

摘要：By using bifunctional ligands bearing carboxylate and N-donor groups, the precursor of (Bu2SnO)-Bu-n undergoes a transformation to yield organotin-oxygen carboxylate clusters, namely, [((Bu2Sn)-Bu-n)(4)(mu(3)-O)(2)(mu(2)-OH)(2)(INA)(2)] (INA = isonicotinate), [((Bu2Sn)-Bu-n)(5)(mu(3)-O)(3)(mu(2)-OH)(2)(INA)(2)], and [((Bu2Sn)-Bu-n)(4)(mu(3)-O)(2)(NA)(4)] (NA = nicotinate), resulting in different geometric building units with two or four extension points. Such organotin-oxygen carboxylate clusters assemble with various CunIn clusters such as a Cu2I2 rhomboid dimer, Cu4I4 cubic tetramer, and Cu6I6 prismatic hexamer to engender various heterometallic cluster coordination polymers.