文献类型：期刊文献

英文题名：Construction of a heterometallic organic framework based on cuprous-halide clusters and lanthanide clusters with CO2 storage and transformation

作者：Miao, Chaolin[1];Su, Tian-E[1]

第一作者：苗超林

通讯作者：Su, TE[1]

机构：[1]Xinxiang Univ, Dept Chem & Chem Engn, Xinxiang 453003, Henan, Peoples R China

第一机构：新乡学院化学化工学院

通讯机构：[1]corresponding author), Xinxiang Univ, Dept Chem & Chem Engn, Xinxiang 453003, Henan, Peoples R China.|[110713]新乡学院化学化工学院;[11071]新乡学院;

年份：2020

卷号：113

外文期刊名：INORGANIC CHEMISTRY COMMUNICATIONS

收录：;WOS:【SCI-EXPANDED(收录号:WOS:000517349100018)】；

语种：英文

外文关键词：Heterometallic organic framework; CO2; Heterogeneous catalyst; Epoxide; Recyclability

摘要：A novel 3D porous heterometallic organic framework based on cuprous-halide clusters and lanthanide clusters, [(Cu4I4)(2)Tb-3(NA)(9)center dot(H2O)(6)center dot(DEF)(6)](n), was successfully designed and synthesized during the solvothermal synthesis. The as-made sample was analysed by many methods. This material has the preferable stability and CO2 capture capacity, so it can be used as a potential heterogeneous catalyst for the chemical fixation of CO2 and epoxides to generate cyclocarbonates. Furthermore, this MOF can preserve its pristine structure after reusing four times.